Conductive zigzag Pd(III)-Br chain complex realized by a multiple-hydrogen-bond approach
Conductive zigzag Pd(III)-Br chain complex realized by a multiple-hydrogen-bond approach
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通过多重氢键方法实现导电之字形Pd(III)-Br链络合物
DOI：
10.1039/d0ce00332h
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发表时间：
2020
期刊：
影响因子：
3.1
通讯作者：
Yamashita Masahiro
中科院分区：
文献类型：
--
作者：
Mian Mohammad Rasel;Afrin Unjila;Iguchi Hiroaki;Takaishi Shinya;Yoshida Takefumi;Miyamoto Tatsuya;Okamoto Hiroshi;Tanaka Hisaaki;Kuroda Shin-ichi;Yamashita Masahiro
首次在[Pd(DabdOH)2Br2H2O]SO4·3H2O(2)中实现了准一维卤素桥联金属配合物中之字形结构和罕见的Pd(III)氧化态的共存。(2S，3S)-2，3-二氨基丁烷-1，4-二醇(2S，3S)-2，3-二氨基丁烷-1，4-二醇(DABDOH)配体与SO42-−和H2O分子之间的链内和链间氢键网络支持这种特殊的结构和电子态。2的室温电导率达到0.05S cm−1。
Coexistence of zigzag structure and the uncommon Pd(III) oxidation state in quasi-1D halogen-bridged metal complexes was realized in a conductive Br-bridged Pd chain complex, [Pd(dabdOH)2Br]SO4·3H2O (2), for the first time. Intra- and interchain hydrogen-bond networks among the (2S,3S)-2,3-diaminobutane-1,4-diol (dabdOH) ligand and SO42− and H2O molecules support this unusual structure and electronic state. The electrical conductivity of 2 reached 0.05 S cm−1 at room temperature.