catena-Poly[[bis-(dimethyl sulfoxide-κO)cerium(III)]tris-(μ(2)-3,5-dinitro-benzoato-κO:O')].
catena-Poly[[bis-(dimethyl sulfoxide-κO)cerium(III)]tris-(μ(2)-3,5-dinitro-benzoato-κO:O')].
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链状聚[[双-(二甲基亚砜-γO)铈(III)]tris-(μ(2)-3,5-二硝基苯甲酰基-γO:O)]。
DOI:
10.1107/s1600536811015947
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发表时间:
2011
期刊:
影响因子:
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通讯作者:
Ng,SeikWeng
中科院分区:
文献类型:
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作者:
Zhou,Fu-Lin;Du,Zhi-Hua;Ng,SeikWeng
The polymeric title compound, [Ce(C7H3N2O6)3(C2H6OS)2]n, exists as a linear chain along [111] as the three dinitrobenzoate anions each engages in bridging adjacent dimethyl sulfoxide (DMSO) coordinated CeIII atoms. The metal atoms are surrounded by eight O atoms in a square-antiprismatic environment. There are two independent formula units in the asymmetric unit. The S atoms of two of the four DMSO molecules are disordered in a 0.926 (3):0.074 (3) ratio.