Molecules to Crystals, Crystals to Molecules ... and Back Again?
Molecules to Crystals, Crystals to Molecules ... and Back Again?
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DOI：
10.1021/cg0680172
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发表时间：
2007
影响因子：
3.8
通讯作者：
M. Zaworotko
中科院分区：
文献类型：
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作者：
M. Zaworotko
多个分子组分的自组装，即模块化自组装，是合成新晶体化合物的一种特别有吸引力的方法，因为它可以通过与现有分子组分的一锅反应来完成，并且可以轻松地微调结构和功能特征。晶体工程面临的挑战和机遇通过关注两类化合物所表现出的结构多样性来说明，这些化合物体现了这些机遇：金属有机网和分子共晶。
Self-assembly of more than one molecular component, modular self-assembly, is a particularly attractive approach to synthesizing new crystalline compounds, because it can be accomplished in one-pot reactions with existing molecular components and it allows for facile fine-tuning of structural and functional features. The challenges and opportunities that face crystal engineering are illustrated by concentrating on the structural diversity that has been exhibited in two classes of compounds that exemplify these opportunities: metal−organic nets and molecular co-crystals.