Mechanism of associatively controlled ligand substitution in square-planar bis(N-alkylsalicylaldiminato)nickel(II) complexes : kinetic, spectroscopic, and thermodynamic characterization of adducts and intermediates
Mechanism of associatively controlled ligand substitution in square-planar bis(N-alkylsalicylaldiminato)nickel(II) complexes : kinetic, spectroscopic, and thermodynamic characterization of adducts and intermediates
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DOI：
10.1021/ic00055a015
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发表时间：
1993-02
影响因子：
4.6
通讯作者：
H. Hoss;H. Elias
中科院分区：
文献类型：
--
作者：
H. Hoss;H. Elias
Spectrophotometric titration was used to determine the equilibrium constants and thermodynamic parameters ΔH o and ΔS o for the addition of mono- and bidentate N-bases to planar four-coordinate bis(N-ethylsalicylaldiminato)nickel(II) derivatives complexes in the solvent acetone. The visible absorption properties of the base adducts are reported.
