A direct anchoring of Anderson-type polyoxometalates in aqueous media with tripodal ligands especially containing the carboxyl group.
A direct anchoring of Anderson-type polyoxometalates in aqueous media with tripodal ligands especially containing the carboxyl group.
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DOI:
10.1039/c3dt53034e
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发表时间:
2014-01
影响因子:
4
通讯作者:
Jiangwei Zhang;Yichao Huang;Jin Zhang;Shan She;J. Hao;Yongge Wei
中科院分区:
文献类型:
--
作者:
Jiangwei Zhang;Yichao Huang;Jin Zhang;Shan She;J. Hao;Yongge Wei
Polyoxometalate-based organic-inorganic hybrids were synthesized by direct modification of the parent Anderson cluster with both the traditional tripodal ligand, CH3C(CH2OH)3, and a novel one containing a carboxyl group, CH3C(CH2OH)2(COOH), which was inaccessible from the traditional self-assembly protocol.