Rhodium(III)‐Catalyzed Directed C−H Bond Naphthylation with 7‐Azabenzonorbornadiene as the Naphthylating Reagent
Rhodium(III)‐Catalyzed Directed C−H Bond Naphthylation with 7‐Azabenzonorbornadiene as the Naphthylating Reagent
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DOI：
10.1002/ajoc.202000029
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发表时间：
2020-02
影响因子：
2.7
通讯作者：
Honghe Li;Weicong Guo;Jijun Jiang;Jun Wang
中科院分区：
文献类型：
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作者：
Honghe Li;Weicong Guo;Jijun Jiang;Jun Wang
本文报道了一种有效的铑（III）催化的C-H键萘化反应，用于合成各种带有萘基取代基的苯胺和苯甲酰胺。底物范围广。产物可以容易地加工成各种合成有用的中间体。据我们所知，使用7-氮杂苯并降冰片二烯通过过渡金属催化的C-H活化来实现萘化之前还没有报道。
An efficient rhodium(III)‐catalyzed C−H bond naphthylation reaction is described for the synthesis of diverse anilides and benzamides bearing naphthyl substituents. The substrate scope is broad. The products could be facilely elaborated to various synthetically useful intermediates. To the best of our knowledge, using 7‐azabenzonorbornadienes to achieve naphthylation via transition‐metal‐catalyzed C−H activation has not been reported before.