Kinetics of the reaction of OH radicals with CH3OH and CD3OD studied by laser photolysis coupled to high repetition rate laser induced fluorescence
Kinetics of the reaction of OH radicals with CH3OH and CD3OD studied by laser photolysis coupled to high repetition rate laser induced fluorescence
复制标题
通过激光光解耦合高重复率激光诱导荧光研究 OH 自由基与 CH3OH 和 CD3OD 的反应动力学
DOI：
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发表时间：
2009
期刊：
影响因子：
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通讯作者：
C. Fittschen
中科院分区：
文献类型：
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作者：
A. Parker;Chaithanya D. Jain;C. Schoemaecker;C. Fittschen
通过测量CH3OH + OH反应的速率常数，验证了以10khz染料激光作为OH荧光激发源耦合激光光解的新实验装置。在相同条件下测定了氘化产物CD3OD + OH的速率常数。
A new experimental set-up coupling laser photolysis to a 10 kHz dye laser as the excitation source for OH fluorescence has been validated by measuring the rate constant of the reaction CH3OH + OH. The rate constant of the deuterated homologue CD3OD + OH has been measured under the same conditions.