Iridium-Catalyzed Addition Reactions of Ethynylsilane to Quinolines and Isoquinolines Activated by Acyl Chloride
Iridium-Catalyzed Addition Reactions of Ethynylsilane to Quinolines and Isoquinolines Activated by Acyl Chloride
复制标题
酰氯活化的铱催化乙炔基硅烷与喹啉和异喹啉的加成反应
DOI：
10.1246/cl.2004.1316
复制
发表时间：
2004
影响因子：
1.6
通讯作者：
R. Yamaguchi
中科院分区：
文献类型：
--
作者：
Y. Yamazaki;K. Fujita;R. Yamaguchi
用铱配合物催化乙炔基三甲基硅烷与酰氯活化的喹啉和异喹啉的加成反应，得到2-三甲基硅基乙炔基-1，2-二氢喹啉和1-三甲基硅基乙炔基-1，2-二氢异喹啉。
Addition reactions of ethynyltrimethylsilane to various quinolines and isoquinolines activated by acyl chloride are catalyzed with a few Ir-complexes to afford 2-trimethylsilyl-ethynyl-1,2-dihydroquinolines and 1-trimethylsilylethynyl-1,2-dihydroisoquinolines in good to high yields.