fac-Tricarbonyl Rhenium(I) Azadipyrromethene Complexes

fac-Tricarbonyl Rhenium(I) Azadipyrromethene Complexes
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fac-三羰基铼(I)氮杂二吡咯亚甲基配合物

DOI:
10.1021/om900552e
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发表时间:
2009
期刊:
影响因子:
2.8
通讯作者:
Thomas G. Gray
Thomas G. Gray
中科院分区:
化学2区
文献类型:
--
作者:
David V. Partyka;Nihal Deligonul;Marlena P. Washington;Thomas G. Gray

文献摘要

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报道了氮杂二吡咯甲烷配体的铼(I)配合物;其中三种已被晶体学表征。自由配体及其金属配合物进行还原性电化学反应。红光吸收是由光学允许跃迁到配位定域LUMO引起的。
Rhenium(I) complexes of azadipyrromethene ligands are reported; three have been characterized crystallographically. The free ligands and their metallo-complexes undergo reductive electrochemistry. Red-light absorption results from optically allowed transitions to a ligand-localized LUMO.