Synthesis of novel photofunctional multinuclear complexes using a coupling reaction.
Synthesis of novel photofunctional multinuclear complexes using a coupling reaction.
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DOI：
10.1039/c5dt01717c
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发表时间：
2015-06
影响因子：
4
通讯作者：
Y. Yamazaki;Tatsuki Morimoto;O. Ishitani
中科院分区：
文献类型：
--
作者：
Y. Yamazaki;Tatsuki Morimoto;O. Ishitani
通过Mizoroki-Heck反应，将各种具有官能团的光功能金属络合物，即溴和乙烯基团，整合成异多核络合物。得到的三核配合物吸收范围广，具有较长的激发态寿命和光催化还原二氧化碳的能力。
Various photofunctional metal complexes with functional groups, i.e. bromo and vinyl groups, were integrated into hetero-multinuclear complexes using the Mizoroki-Heck reaction. The obtained trinuclear complexes absorb a wide range of visible light and have a long excited state lifetime and the photocatalytic ability to obtain CO2 reduction.