Hydrolysis of Iron(III)…Chaotic Olation Versus Nucleation
Hydrolysis of Iron(III)…Chaotic Olation Versus Nucleation
复制标题
铁 (III) 的水解…混沌化与成核
DOI：
10.1080/02603598408078138
复制
发表时间：
1984
影响因子：
5.4
通讯作者：
W. Schneider
中科院分区：
文献类型：
--
作者：
W. Schneider
摘要在中等温度下，铁（Ⅲ）在水溶液中水解产生各种溶胶、凝胶、无定形或结晶沉淀。产物分布反映了快速质子转移、氧化和聚集反应的相互作用。在均匀溶液中，在有利的条件下形成具有明确结构的多核氧代羟合物。在氯化物溶液中发现了具有β-FeO（OH）结构的多核物种。
Abstract At moderate temperatures, a variety of sols, gels, amorphous or crystalline precipitates emerge from hydrolysis of iron(III) in aqueous solution. The product distribution reflects the interplay of fast proton transfer, olation and aggregation reactions. Polynuclear oxohydroxocomplexes with well-defined structures are formed under favorable circumstances in homogeneous solution. Polynuclear species with β-FeO(OH) structures have been identified in chloride solutions.