Sequential cross-metathesis/phosphorus-based olefination: stereoselective synthesis of 2,4-dienoates

Sequential cross-metathesis/phosphorus-based olefination: stereoselective synthesis of 2,4-dienoates
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DOI:
10.1016/j.tetlet.2007.06.031
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发表时间:
2007-07-30
影响因子:
1.8
通讯作者:
Andrade, Rodrigo B.
Andrade, Rodrigo B.
中科院分区:
化学4区
文献类型:
--
作者:
Paul, Tapas;Andrade, Rodrigo B.

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通过使用市售试剂以良好产率对烯烃交叉复分解(CM)与基于磷的烯烃化反应(Wittig和Horner-Wadsworth-Emmons)进行排序,以立体选择性方式制备了多种立体定向的2,4-二烯酸酯。(c)2007爱思唯尔有限公司保留所有权利。
A variety of stereodefined 2,4-dienoates have been prepared in a stereoselective manner by sequencing olefin cross-metathesis (CM) with phosphorus-based olefination reactions (Wittig and Horner-Wadsworth-Emmons) in good yield using commercially available reagents. (c) 2007 Elsevier Ltd. All rights reserved.