Synthesis and application of novel crosslinking polyamine dyes with good dyeing performance
Synthesis and application of novel crosslinking polyamine dyes with good dyeing performance
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DOI：
10.1016/j.dyepig.2006.10.012
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发表时间：
2008-01-01
影响因子：
4.5
通讯作者：
Li, Qian
中科院分区：
文献类型：
--
作者：
Li, Yingling;Zhang, Shufen;Li, Qian
使用四亚乙基五胺合成了新型交联染料。以苯甲酰H-酸磺酰胺为基础，分别与苯胺、对甲苯胺、邻甲氧基苯胺、对氨基苯酚、对硝基苯胺、间氨基苯磺酸、l-氨基萘-5-磺酸的重氮盐反应，制备了一系列新型红色多胺交联染料D-1-D-7。通过四乙烯五胺与 C.I. 的反应合成了两种新型多胺交联染料。分别为活性红2和4-(4-氯磺酰基-苯基亚肼基)-3-甲基-1-苯基-5-吡唑啉酮。用这些多胺染料染色的丝绸通过交联剂2-氯-4,6-二(氨基苯-4'-β-硫酸基乙砜)-1,3,5-s-三嗪进行固定，其充当纤维和染料分子之间的桥梁。这些染料的交联反应率均达到95%以上，高亲和力交联染料的整体固色效率达到98%以上。染色样品表现出良好的耐洗和耐摩擦牢度。 ((c)) 2006 Elsevier Ltd. 保留所有权利。
Novel crosslinking dyes were synthesized using tetraethylenepentamine. A series of novel red polyamine crosslinking dyes D-1-D-7 based on benzoyl H-acid sulfonamide were prepared via the reaction of it with diazo salts of aniline, p-toluidine, o-methoxyaniline, p-aminophenol, p-nitraniline, m-aminobenzene sulfonic acid, l-aminonaphthalene-5-sulfonic acid, respectively. Two novel polyamine crosslinking dyes were synthesized via the reactions of tetraethylenepentamine with C.I. Reactive Red 2 and 4-(4-chlorosulfonyl-phenylhydrazono)-3-methyl-1-phenyl-5-pyrazolone, respectively. The silk dyed with these polyamine dyes was fixed via crosslinking agent 2-chloro-4,6-di(aminobenzene-4 '-beta-sulfatoethylsulfone)- 1,3,5-s-triazine, which acted as a bridge between the fibre and the dye molecule. The crosslinking reaction ratio of these dyes reached more than 95%, and the overall fixation efficiency of the crosslinking dye of high affinity was more than 98%. The dyed samples exhibited good fastness to washing and rubbing. ((c)) 2006 Elsevier Ltd. All rights reserved.