Hydrogen-bridged bis(silylene) complexes of ruthenium and iron: synthesis, structures and multi-centre bonding interactions at the M-Si-H-Si four-membered ring
Hydrogen-bridged bis(silylene) complexes of ruthenium and iron: synthesis, structures and multi-centre bonding interactions at the M-Si-H-Si four-membered ring
复制标题
钌和铁的氢桥双(亚硅基)配合物：合成、结构和M-Si-H-Si四元环的多中心键合相互作用
DOI：
10.1039/c7dt00505a
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发表时间：
2017
影响因子：
4
通讯作者：
Hiromi Tobita
中科院分区：
文献类型：
--
作者：
Hisako Hashimoto;Katsuto Komura;Takatoshi Ishizaki;Yuto Odagiri;Hiromi Tobita
首次合成了含8族金属的氢桥联双(硅烯)Ru和Fe配合物，并通过核磁共振光谱、X-射线单晶学和理论计算阐明了它们在M-Si-H-Si部分的稀有四元环结构和多中心成键作用。
Hydrogen-bridged bis(silylene) complexes of ruthenium and iron were synthesized as the first examples of this type containing Group 8 metals and their rare four-membered ring structures and multi-center bonding interactions at the M–Si–H–Si moiety were clarified by NMR spectroscopy, X-ray crystallography and theoretical calculations.