Generation of diamondoid hydrocarbons as confined compounds in SAPO-34 catalyst in the conversion of methanol
Generation of diamondoid hydrocarbons as confined compounds in SAPO-34 catalyst in the conversion of methanol
复制标题
甲醇转化过程中 SAPO-34 催化剂中作为受限化合物生成类金刚石碳氢化合物
DOI：
10.1039/c2cc17676a
复制
发表时间：
2012-01-01
影响因子：
4.9
通讯作者：
Liu, Zhongmin
中科院分区：
文献类型：
--
作者：
Wei, Yingxu;Li, Jinzhe;Liu, Zhongmin
SAPO-34分子筛中金刚烷烃的生成及其限制导致甲醇转化诱导期较长，催化剂失活较快。在8环SAPO催化剂笼形条件下，通过瓶中式合成，甲醇转化可制得金刚烷和甲基金刚烷。
Formation of adamantane hydrocarbons and their confinement in SAPO-34 caused the long induction period and the quick catalyst deactivation in methanol conversion. Via ship-in-a-bottle synthesis, adamantane and methyladamantanes could be produced from methanol conversion in the cage of 8-ring SAPO catalysts under very mild reaction conditions.