Molar refractivity and interactions in solutions I. Molar refractivity of some monovalent ions in aqueous and dimethyl sulfoxide solutions
Molar refractivity and interactions in solutions I. Molar refractivity of some monovalent ions in aqueous and dimethyl sulfoxide solutions
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摩尔折射率和溶液中的相互作用 I. 水溶液和二甲基亚砜溶液中某些单价离子的摩尔折射率
DOI:
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发表时间:
2012
期刊:
影响因子:
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通讯作者:
P. Pacák
中科院分区:
文献类型:
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作者:
P. Pacák
The mplar refractivity reflects arrangements of the electron shells of ions in molecules and yields information about the electronic polarization of ions. The combination of ions to form molecules in a gas or a crystal or complex ions in solution is always accompanied by a change in the properties of the ions themselves. The molar refractivity reflects the changes in the properties due to polarization or to deformation of the electron shells of the ions under the influence of the electric fields of neighbouring ions. The molar refractivity [R] (cm mol ) is defined by the Lorenz—Lorentz expression