Molar refractivity and interactions in solutions I. Molar refractivity of some monovalent ions in aqueous and dimethyl sulfoxide solutions

Molar refractivity and interactions in solutions I. Molar refractivity of some monovalent ions in aqueous and dimethyl sulfoxide solutions
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摩尔折射率和溶液中的相互作用 I. 水溶液和二甲基亚砜溶液中某些单价离子的摩尔折射率

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发表时间:
2012
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通讯作者:
P. Pacák
P. Pacák
中科院分区:
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作者:
P. Pacák

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分子的极化率反映了离子在分子中的电子层的排列,并提供了离子的电子极化信息。离子结合形成气体中的分子或溶液中的晶体或复合离子总是伴随着离子本身性质的变化。摩尔电子活度反映了由于极化或在相邻离子的电场影响下离子的电子壳层的变形而引起的性质变化。摩尔活度[R](cm mol)由Lorenz-Lorentz表达式定义
The mplar refractivity reflects arrangements of the electron shells of ions in molecules and yields information about the electronic polarization of ions. The combination of ions to form molecules in a gas or a crystal or complex ions in solution is always accompanied by a change in the properties of the ions themselves. The molar refractivity reflects the changes in the properties due to polarization or to deformation of the electron shells of the ions under the influence of the electric fields of neighbouring ions. The molar refractivity [R] (cm mol ) is defined by the Lorenz—Lorentz expression