Interfacial morphology and corrosion resistance of Fe-B cast steel containing chromium and nickel in liquid zinc

Interfacial morphology and corrosion resistance of Fe-B cast steel containing chromium and nickel in liquid zinc
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DOI:
10.1016/j.corsci.2011.05.020
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发表时间:
2011-09-01
期刊:
影响因子:
8.3
通讯作者:
Ma, Shengchao
Ma, Shengchao
中科院分区:
材料科学1区
文献类型:
--
作者:
Ma, Shengqiang;Xing, Jiandong;Ma, Shengchao

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研究了低碳铁硼铸钢在520 ℃锌浴中的界面形貌和耐蚀性。结果表明,高铬高镍的铁硼铸钢具有最好的耐锌液腐蚀性能。腐蚀层由γ-Fe_3Zn_(10)、δ-FeZn_(10)、xi-FeZn_(13)和η-Zn组成。Fe-B铸钢的腐蚀行为包括以下过程:Cr和Ni的优先浸出和溶解,锌原子扩散控制的Fe-Zn化合物的形成,以及在液态锌腐蚀下,没有α-(Fe,Cr)基体支撑作用的硼化物剥落。皇冠版权所有(C)2011由爱思唯尔有限公司出版。保留所有权利。
The interfacial morphology and corrosion resistance of low carbon Fe-B cast steels in zinc bath at 520 degrees C were investigated. The results show Fe-B cast steel containing high Cr and Ni exhibits the best corrosion resistance to liquid zinc. The corrosion layers are composed of Gamma-Fe3Zn10, delta-FeZn10, xi-FeZn13 and eta-Zn. The corrosion behaviour of Fe-B cast steels includes the following processes: the preferential leach and dissolution of Cr and Ni, the formation of Fe-Zn compounds controlled by zinc atom diffusion, and the spalling of borides without the supporting role of alpha-(Fe, Cr) matrix corroded by liquid zinc. Crown Copyright (C) 2011 Published by Elsevier Ltd. All rights reserved.