CHARACTERIZATION OF 9,10 ANTHRAQUINONE THIN-FILMS
CHARACTERIZATION OF 9,10 ANTHRAQUINONE THIN-FILMS
复制标题
DOI：
10.1016/0040-6090(91)90280-b
复制
发表时间：
1991-01-01
期刊：
影响因子：
2.1
通讯作者：
BENHIDA, S
中科院分区：
文献类型：
--
作者：
LATEF, A;BERNEDE, JC;BENHIDA, S
通过红外吸收、X 射线衍射和化学分析电子能谱 (ESCA)、扫描电子显微镜和光学吸收研究了真空沉积的 9,10 蒽醌薄膜。 研究发现，在适当的退火后，任何种类的基底都可以获得结晶的9,10蒽醌薄膜。 单斜晶体的 c 轴方向基本上垂直于基材的平面。发现从 ESCA 线推导出的结合能和红外吸收带的频率与粉末参考非常一致。 光吸收可以与约3.25eV的间隙相关。
9,10 Anthraquinone thin films deposited under vacuum were investigated by IR absorption, X-ray diffraction and electron spectroscopy for chemical analysis (ESCA), scanning electron microscopy and optical absorption. It was found that crystallized 9,10 anthraquinone thin films are obtained for any kind of substrate after appropriate annealing. The c axis orientation of the monoclinic crystallites is essentially perpendicular to the plane of the substrate.The binding energies deduced from the ESCA lines and the frequencies of the IR absorption bands were found to be in good agreement with the powder reference. Optical absorption may be associated with a gap of about 3.25 eV.