Rhodium(I) complexes with N-heterocyclic carbenes bearing a 2,3,4,5-tetraphenylphenyl and its higher dendritic frameworks.
Rhodium(I) complexes with N-heterocyclic carbenes bearing a 2,3,4,5-tetraphenylphenyl and its higher dendritic frameworks.
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DOI：
10.1039/b612385f
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发表时间：
2007-01
影响因子：
4.9
通讯作者：
中科院分区：
文献类型：
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作者：
合成了含2，3，4，5-四苯基及其树枝状骨架的N-杂环卡宾铑（I）配合物，并将其用于铑催化的α，β-不饱和酮的硅氢加成反应，显示出高的1，4-加成选择性。
Novel rhodium(I) complexes with N-heterocyclic carbenes bearing a 2,3,4,5-tetraphenylphenyl and its higher dendritic frameworks were synthesized and the complexes were used as catalysts in rhodium-catalyzed hydrosilylation of alpha,beta-unsaturated ketones to show high 1,4-adduct selectivity.