Structural Principles in the Chemistry of Heteropolycompounds
Structural Principles in the Chemistry of Heteropolycompounds
复制标题
杂多化合物化学的结构原理
DOI：
10.1070/rc1974v043n07abeh001828
复制
发表时间：
1974
影响因子：
7.7
通讯作者：
V. Spitsyn
中科院分区：
文献类型：
--
作者：
L. P. Kazanskii;E. A. Torchenkova;V. Spitsyn
根据最新的X射线衍射研究结果，对在溶液中形成的、以结晶状态从后者中分离出来的不同类型的杂多化合物进行了分析和分类。简要讨论了导致目前关于杂多化合物(一大类络合物)结构的观点的物理化学和研究技术。在结构考虑的基础上，考察了杂多化合物配位球中一个或几个金属原子被取代的可能性。讨论了杂多化合物化学的主要发展趋势和存在的问题。参考文献包括191篇参考文献。
Different types of heteropolycompounds, which are formed in solutions and can be isolated from the latter in a crystalline state, have been analysed and classified on the basis of the results of latest X-ray diffraction studies. The physicochemical and research techniques which have led to the current views on the structures of heteropolycompounds (a large class of complexes) are briefly considered. The possibilities which arise on substitution of one or several metal atoms in the coordination sphere of the heteropolycompound are examined on the basis of structural considerations. The principal trends and problems in the chemistry of heteropolycompounds are discussed. The bibliography includes 191 references.