The electron spin resonance spectrum of the fulvalene radical anion
The electron spin resonance spectrum of the fulvalene radical anion
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富瓦烯自由基阴离子的电子自旋共振谱
DOI：
10.1039/p29810000747
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发表时间：
1981
期刊：
影响因子：
--
通讯作者：
J. Lusztyk
中科院分区：
文献类型：
--
作者：
A. G. Davies;J. Giles;J. Lusztyk
富瓦烯阴离子是由环戊二烯基锂或富瓦烯二酸锂在氧气中氧化，通过富瓦烯与钠还原或电解得到的。急诊室。光谱显示(H-2，-2‘，-5，-5’)1.55，a(H-3，-3‘，-4，-4’)3.70，a(13C-1，-1‘)2.90，a(13C-2，-2’，-5，-5‘)1.40，和(13C-3，-3’，-4，-4‘)2.15G。a(H)的归属基于HMO模型，和那些(13C)关于与泽川-川村-加藤的关系。
The fulvalene radical anion has been prepared by the oxidation of cyclopentadienyl-lithium or dilithium fulvalenediide with oxygen, and by the reduction of fulvalene with sodium, or electrolytically. The e.s.r. spectrum shows a(H-2,-2′,-5,-5′) 1.55, a(H-3,-3′,-4,-4′) 3.70, a(13C-1,-1′) 2.90, a(13C-2,-2′,-5,-5′) 1.40, and a(13C-3,-3′,-4,-4′) 2.15 G. The assignments for a(H) are based on the HMO model, and those for a(13C) on the Yonezawa–Kawamura–Kato relationship.