An improved route to 1,2,4-trioxanes using tin(IV) as a hydrogen equivalent
An improved route to 1,2,4-trioxanes using tin(IV) as a hydrogen equivalent
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DOI：
10.1039/p19920003383
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发表时间：
1992
期刊：
影响因子：
--
通讯作者：
J. Cai;A. G. Davies
中科院分区：
文献类型：
--
作者：
J. Cai;A. G. Davies
Bloodworth's route to the 1,2,4-trioxanes has been duplicated using tin(IV) as a hydrogen equivalent throughout. Thus a tetraallyltin compound is treated with singlet oxygen to give a tetraallylperoxytin compound; this adds to an aldehyde to give the tin derivative of a peroxyhemiacetal, and this tin alkoxide undergoes ring-closing intramolecular addition to the olefinic group in the presence of mercury (II) acetate to give the 1,2,4-trioxane.
