Direct proof for electrochemical substitution of surface hydrogen of boron-doped diamond electrode by TOF-ESD method
Direct proof for electrochemical substitution of surface hydrogen of boron-doped diamond electrode by TOF-ESD method
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DOI：
10.1246/cl.2003.1050
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发表时间：
2003-11-05
影响因子：
1.6
通讯作者：
Uosaki, K
中科院分区：
文献类型：
--
作者：
Yagi, I;Ogai, K;Uosaki, K
使用 TOF-ESD 方法证实了电化学析氢过程中硼 (B) 掺杂金刚石电极上表面氢的取代。结果表明，B掺杂金刚石电化学析氢过程中溶液中D+(H+)被还原，表面-H(D)被D(H)取代。
The substitution of surface hydrogen on boron (B)-doped diamond electrodes during electrochemical hydrogen evolution was confirmed using TOF-ESD method. The results show that surface-H(D) was substituted by D(H) as a result of the reduction of D+(H+) in solution during the electrochemical hydrogen evolution at the B-doped diamond.