Synthesis and characterization of the bulky thiolate complexes [Li(OEt2)3][Ti{S-2,4,6-iso-Pr3C6H2}4] and Li(THF)3(S-2,4,6-tert-Bu3C6H2)]. Comparisons of M-SR and M-OR bonding
Synthesis and characterization of the bulky thiolate complexes [Li(OEt2)3][Ti{S-2,4,6-iso-Pr3C6H2}4] and Li(THF)3(S-2,4,6-tert-Bu3C6H2)]. Comparisons of M-SR and M-OR bonding
复制标题
大体积硫醇盐配合物[Li(OEt2)3][Ti{S-2,4,6-iso-Pr3C6H2}4]和Li(THF)3(S-2,4,6-tert-Bu3C6H2)的合成和表征
DOI:
10.1021/ic00264a019
复制
发表时间:
1987
期刊:
影响因子:
--
通讯作者:
P. P. Power
中科院分区:
文献类型:
--
作者:
G. Sigel;P. P. Power
[Li(OEt 2 ) 3 ] [Ti{S-2,4,6-i-Pr 3 C 6 H 2 } 4 ] cristallise dans le systeme orthorhombique, groupe d'espace C222 1 et sa structure est affinee jusqu'a R=0,053. [Li(THF) 3 (S-2,4,6-t-Bu 3 C 6 H 2 )] cristallise dans le systeme triclinique, groupe d'espace P1 avec R=0,084