Amination of aryl chlorides in water catalyzed by cyclopalladated ferrocenylimine complexes with commercially available monophosphinobiaryl ligands
Amination of aryl chlorides in water catalyzed by cyclopalladated ferrocenylimine complexes with commercially available monophosphinobiaryl ligands
复制标题
DOI：
10.1016/j.tetlet.2006.12.130
复制
发表时间：
2007-02-26
影响因子：
1.8
通讯作者：
Wu, Yang-Jie
中科院分区：
文献类型：
--
作者：
Xu, Chen;Gong, Jun-Fang;Wu, Yang-Jie
人们发现，易于获得、空气和水分稳定的环钯二茂铁基亚胺络合物 3 是一种高活性单组分预催化剂，用于在廉价的 KOH 和 t-BuOH 分别作为碱和添加剂的情况下，在水中对芳基氯进行胺化。 (c) 2007 Elsevier Ltd. 保留所有权利。
The easily accessible, air- and moisture-stable cyclopalladated ferrocenylimine complex 3 was found to be a highly active one-component precatalyst for the amination of aryl chlorides in water in the presence of inexpensive KOH and t-BuOH as a base and an additive, respectively. (c) 2007 Elsevier Ltd. All rights reserved.