Redox systems under nano-space control
Redox systems under nano-space control
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发表时间：
2006
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通讯作者：
平尾 俊一
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作者：
平尾 俊一
氧化还原系统通过d，？-结合。醌二亚胺衍生物的共轭络合物在导电聚合物传感器中实现最终放大：隔离的纳米级通路。含金属？共轭材料。氧化还原活性结构和富碳钌络合物作为分子导线的模型。分子金属线由线性金属原子链构建，由低聚吡啶酰胺配体支撑。金属组装大分子体系中的多电子氧化还原催化剂通过协调控制的氧化还原系统。显示多步/多电子氧化还原行为的三钌簇低聚物。基于表面配位化学的氧化还原活性多层金属配合物的分子结构通过可设计的生物大分子的程序化金属阵列。金属公司的合作和响应识别外部刺激。聚联萘二甲酸酯的可控氧化偶联合成通过分子链控制的氧化还原系统。纳米麦卡诺利用轮烷的互锁结构对氧化还原反应的空间控制含金属的星星和超支化聚合物螺旋肽衍生物在单分子水平上的电子性质使用抗体的抗原结合位点和抗体超分子的功能化构建氧化还原诱导系统。
Redox Systems via d,?-Conjugation.- Conjugated Complexes with Quinonediimine Derivatives.- Realizing the Ultimate Amplification in Conducting Polymer Sensors: Isolated Nanoscopic Pathways.- Metal-Containing ?-Conjugated Materials.- Redox Active Architectures and Carbon-Rich Ruthenium Complexes as Models for Molecular Wires.- Molecular Metal Wires Built from a Linear Metal Atom Chain Supported by Oligopyridylamido Ligands.- Multielectron Redox Catalysts in Metal-Assembled Macromolecular Systems.- Redox Systems via Coordination Control.- Triruthenium Cluster Oligomers that Show Multistep/Multielectron Redox Behavior.- Molecular Architecture of Redox-Active Multilayered Metal Complexes Based on Surface Coordination Chemistry.- Programmed Metal Arrays by Means of Designable Biological Macromolecules.- Metal-Incorporated Hosts for Cooperative and Responsive Recognition to External Stimulus.- Synthesis of Poly(binaphthol) via Controlled Oxidative Coupling.- Redox Systems via Molecular Chain Control.- Nano Meccano.- Through-Space Control of Redox Reactions Using Interlocked Structure of Rotaxanes.- Metal-Containing Star and Hyperbranched Polymers.- Electronic Properties of Helical Peptide Derivatives at a Single Molecular Level.- Construction of Redox-Induced Systems Using Antigen-Combining Sites of Antibodies and Functionalization of Antibody Supramolecules.