The [4+3]-cycloaddition/quasi-Favorskii process. Synthesis of the carbocyclic core of tricycloclavulone
The [4+3]-cycloaddition/quasi-Favorskii process. Synthesis of the carbocyclic core of tricycloclavulone
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DOI：
10.1021/ol050598l
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发表时间：
2005-06-23
期刊：
影响因子：
5.2
通讯作者：
Wacharasindhu, S
中科院分区：
文献类型：
--
作者：
Harmata, M;Wacharasindhu, S
由2,5-二溴环戊酮与环戊二烯反应生成的[4 + 3]-环加合物经准favorskii重排和开环、闭环复分解序列转化为前列腺素类三环戊酮的碳环核心。
The [4 + 3]-cycloadduct derived from the reaction of 2,5-dibromocyclopentanone with cyclopentadiene was converted via a quasi-Favorskii rearrangement and ring-opening, ring-closing metathesis sequence to the carbocyclic core of the prostanoid tricycloclavulone.