Living catalyzed-chain-growth polymerization and block copolymerization of isoprene by rare-earth metal allyl precursors bearing a constrained-geometry-conformation ligand
Living catalyzed-chain-growth polymerization and block copolymerization of isoprene by rare-earth metal allyl precursors bearing a constrained-geometry-conformation ligand
复制标题
带有受限几何构象配体的稀土金属烯丙基前体对异戊二烯的活性催化链增长聚合和嵌段共聚
DOI：
10.1039/b926813h
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发表时间：
2010-01-01
影响因子：
4.9
通讯作者：
Li, Xiaofang
中科院分区：
文献类型：
--
作者：
Jian, Zhongbao;Cui, Dongmei;Li, Xiaofang
氨基苯基官能化的稀土金属烯丙基介导的阳离子体系显示高顺式-1，4异戊二烯聚合的选择性，和活性可逆和快速链转移到铝添加剂。
Aminophenyl functionalized cyclopentadienyl ligated rare-earth metal allyl mediated cationic systems display high cis-1,4 selectivity for the polymerization of isoprene, and living reversible and rapid chain transfer to aluminium additives.