High pseudocapacitive cobalt carbonate hydroxide films derived from CoAl layered double hydroxides

High pseudocapacitive cobalt carbonate hydroxide films derived from CoAl layered double hydroxides
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由 CoAl 层状双氢氧化物衍生的高赝电容碳酸钴氢氧化物薄膜

DOI:
10.1039/c2nr30617d
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发表时间:
2012-01-01
期刊:
影响因子:
6.7
通讯作者:
Duan, Xue
Duan, Xue
中科院分区:
材料科学2区
文献类型:
--
作者:
Lu, Zhiyi;Zhu, Wei;Duan, Xue

文献摘要

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以煤- ldh纳米片为原料,采用碱刻蚀法去除Al阳离子,制备了介孔碳酸钴氢氧化物(MPCCH)纳米片。基本蚀刻电极表现出增强的比电容(在5 mA cm(-2)时1075 F g(-1))和更高的倍率能力和循环稳定性(在2000次循环后保持92%)。
A thin nanosheet of mesoporous cobalt carbonate hydroxide (MPCCH) has been fabricated from a CoAl-LDH nanosheet following removal of the Al cations by alkali etching. The basic etched electrode exhibits enhanced specific capacitance (1075 F g(-1) at 5 mA cm(-2)) and higher rate capability and cycling stability (92% maintained after 2000 cycles).