Application of Organocerium Reagents for the Efficient Conversion of Z-α,β-Unsaturated Weinreb Amides to Z-α,β-Unsaturated Ketones
Application of Organocerium Reagents for the Efficient Conversion of Z-α,β-Unsaturated Weinreb Amides to Z-α,β-Unsaturated Ketones
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DOI：
10.1246/cl.2005.470
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发表时间：
2005-02
影响因子：
1.6
通讯作者：
S. Kojima;Tsugihiko Hidaka;A. Yamakawa
中科院分区：
文献类型：
--
作者：
S. Kojima;Tsugihiko Hidaka;A. Yamakawa
研究了富Z不饱和Weinreb酰胺与有机锂和有机铈试剂的反应。综合考虑反应的几何构型保持程度和反应的清洁程度，有机铈试剂对Z-α，β-不饱和酮的转化更有效。
The reactions ofZ-rich unsaturated Weinreb amides with organolithium and organocerium reagents were examined. Taking in consideration both the extent of geometry retention and cleanness of the reaction, organocerium reagents were more effective for the conversion to Z-α,β-unsaturated ketones.