Handbook of Organopalladium Chemistry for Organic Synthesis
Handbook of Organopalladium Chemistry for Organic Synthesis
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DOI：
10.1055/s-2003-37640
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发表时间：
2003
期刊：
影响因子：
--
通讯作者：
D. Harrowven
中科院分区：
文献类型：
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作者：
D. Harrowven
有机钯化学对有机化学家解决合成问题的方式产生了深远的影响。近年来，已经发表了数千篇研究文章，涉及有机合成中钯介导的反应的各个方面。这本“手册”以合乎逻辑且易于理解的形式总结了这些内容，为我们的社区提供了出色的服务。此外，经验丰富的用户和新手都应该发现本书内容丰富，因为来自世界各地的许多领先从业者都为这项伟大的事业做出了贡献。文献覆盖范围截至 2000 年，这本两卷本的贡献者约有 130 名。本书分为 10 个部分，并进一步细分为更易于管理的部分。第一部分通过历史回顾和对金属及其配合物的基本性质和反应的回顾来正确看待钯化学。钯化合物的化学计量制备和原位生成见第二部分。常用催化剂的物理和化学性质与一些更奇特的钯配合物一起讨论，为这些大量且常常浮夸的文献提供了简洁而有用的总结。不对称配体也被强调，尽管此时讨论并未扩展到原位生成的许多催化剂体系。
Organopalladium chemistry has had a profound impact on the way that organic chemists tackle synthetic problems. In recent years thousands of research articles have been published dealing with various aspects of palladium mediated reactions in organic synthesis. This ‘handbook’does an outstanding service to our community by summarising these in a logical and accessible form. Moreover, both experienced users and novices alike should find the work informative as many of the leading practitioners from around the globe have contributed to this monumental undertaking. Literature coverage is to 2000 and there are some 130 contributors to the two-volume tome. The book is divided into 10 Parts, which are further sub-divided into more manageable sections. Part I places palladium chemistry in perspective with a historical overview and a review of the fundamental properties and reactions of the metal and its complexes. The stoichiometric preparation and in situ generation of palladium compounds follows in Part II. Physical and chemical properties of commonly employed catalysts are discussed alongside some of the more exotic palladium complexes, providing a concise and useful summary of this vast and often turgid literature. Asymmetric ligands are also highlighted, though at this juncture the discussion does not extend to the many catalyst systems generated in situ.