REGIOSELECTIVE AND ENANTIOSELECTIVE EPOXIDATION CATALYZED BY METALLOPORPHYRINS
REGIOSELECTIVE AND ENANTIOSELECTIVE EPOXIDATION CATALYZED BY METALLOPORPHYRINS
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DOI：
10.1126/science.8367724
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发表时间：
1993-09-10
期刊：
影响因子：
56.9
通讯作者：
BRAUMAN, JI
中科院分区：
文献类型：
--
作者：
COLLMAN, JP;ZHANG, XM;BRAUMAN, JI
本文讨论了金属卟啉催化的区域选择性和对映选择性环氧化的最新进展，并解释了该领域的仿生前身及其与合成应用的相关性。对已研究的催化剂进行分类可以得出有关该领域发展的有用结论。特别是，最有前途的仿生催化剂和实用催化剂都来自可以通过方便的合成方法进行系统修改的系统。
Recent progress in regioselective and enantioselective epoxidations catalyzed by metalloporphyrins is discussed here, with an explanation of the biomimetic antecedents of this area and its relevance to synthetic applications. Classification of the catalysts that have been studied allows useful conclusions to be drawn about the development of this field. In particular, both the most promising biomimetic and practical catalysts have arisen from systems that can be systematically modified by convenient synthetic methodology.