Synthesis of 1H-Diphosphirene, Phosphorus-Carbon Cage and 2,3-Dihydro-1,2,3-Triphosphete Tungsten Complexes

Synthesis of 1H-Diphosphirene, Phosphorus-Carbon Cage and 2,3-Dihydro-1,2,3-Triphosphete Tungsten Complexes
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1H-二磷烯、磷-碳笼和2,3-二氢-1,2,3-三磷酸钨配合物的合成

DOI:
10.1080/10426509708545680
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发表时间:
1997
影响因子:
1.3
通讯作者:
R. Streubel
R. Streubel
中科院分区:
化学4区
文献类型:
--
作者:
Udo Rohde;H. Wilkens;R. Streubel

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摘要:通过在各种磷炔存在下热分解不同的 2H-氮杂磷烯配合物,合成了新的 1H-二磷烯和 2,3-二氢-1,2,3-三磷酸钨配合物。如果使用五甲基环戊二烯基取代的2H-氮杂磷烯络合物和烷基取代的磷炔,则获得新型磷-碳笼络合物。
Abstract: New lH-diphosphirene and 2,3-dihydro-l,2,3-triphosphete tungsten complexes have been synthesized, by thermal decomposition of different 2H-azaphosphirene complexes in the presence of various phosphaalkynes. Novel phosphorus-carbon cage complexes were obtained, if a pentamethylcyclopentadienyl-substituted 2H-azaphosphirene complex and alkyl-substituted phosphaalkynes were employed.