Development of a boron-dipyrromethene-Cu2+ ensemble based colorimetric probe toward hydrogen sulfide in aqueous media

Development of a boron-dipyrromethene-Cu2+ ensemble based colorimetric probe toward hydrogen sulfide in aqueous media
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开发基于硼-二吡咯亚甲基-Cu2整体的比色探针来检测水介质中的硫化氢

DOI:
10.1016/j.tetlet.2011.07.004
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发表时间:
2011-09-28
影响因子:
1.8
通讯作者:
Zhu, Yi-Zhun
Zhu, Yi-Zhun
中科院分区:
化学4区
文献类型:
--
作者:
Gu, Xianfeng;Liu, Chunhua;Zhu, Yi-Zhun

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本文报道了一种基于硼-二吡咯亚甲基-Cu ~(2+)体系的比色探针,用于水介质中硫化氢的检测。配合物1-Cu(II)能够相对于其它阴离子和硫醇选择性地感测硫化氢,随后释放化合物1以在水溶液(HEPES(4-(2-羟乙基)-1-哌嗪乙磺酸)缓冲液,50 mM,pH 7.4,5%DMSO)中产生显著的UV吸收变化。(C)2011年由Elsevier Ltd.出版
A boron-dipyrromethene-Cu2+ ensemble based colorimetric probe for detection of hydrogen sulfide in aqueous media is reported. Complex 1-Cu(II) is able to selectively sense hydrogen sulfide over other anions and thiols followed by the release of compound 1 to give a remarkable change of UV absorption in aqueous solution (HEPES (4-(2-hydroxyethyl)-1-piperazineethanesulfonic acid) buffer, 50 mM, pH 7.4, 5% DMSO). (C) 2011 Published by Elsevier Ltd.