A facile synthetic route to a third-generation dendrimer with generation-specific functional aryl bromides

A facile synthetic route to a third-generation dendrimer with generation-specific functional aryl bromides
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DOI:
10.1021/ol005972q
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发表时间:
2000-06-01
期刊:
影响因子:
5.2
通讯作者:
Schluter, AD
Schluter, AD
中科院分区:
化学1区
文献类型:
--
作者:
Bo, ZS;Schäfer, A;Schluter, AD

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描述了分别在第一、第二或第三代中选择性地携带一个芳基溴官能团的三种第三代树枝状聚合物的合成。这些功能,无论它们的位置,可以通过铃木交叉偶联化学与p-叔丁基苯硼酸酯进行化学修饰。
[GRAPHICS]The synthesis of three third-generation dendrimers that selectively carry one aryl bromide functional group in the first, second, or third generation, respectively, is described. These functions, regardless of their location, can be chemically modified by Suzuki cross-coupling chemistry with p-Tert-butylbenzene boronic ester.