Preparation of molecular selective GO/DTiO2-PDA-PEI composite nanofiltration membrane for highly pure dye separation
Preparation of molecular selective GO/DTiO2-PDA-PEI composite nanofiltration membrane for highly pure dye separation
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DOI：
10.1016/j.memsci.2019.117727
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发表时间：
2020-03
影响因子：
9.5
通讯作者：
Yanqing Xu;Guibin Peng;Junbin Liao;Jiangnan Shen;Cong-jie Gao
中科院分区：
文献类型：
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作者：
Yanqing Xu;Guibin Peng;Junbin Liao;Jiangnan Shen;Cong-jie Gao
The state-of-the-art graphene oxide (GO) has been wildly used in water purification due to its tunable nanoscale interlayer between the two-dimensional nanosheets. However, the structural instability and flux decline performances significantly limit the practical application of GO-based membranes. Herein, a novel GO/DTiO2-PDA-PEI (dopamine modified TiO2) composite nanofiltration membrane has been preparedviaa multi-coupled strategy, combining with the self-assembly, copolymerization and surface grafting. Tuning the nanoscale interspace between the GO nanosheets, and constructing the membrane with positively charged surface and negatively charged subsurface, the loose GO/DTiO2-PDA-PEI composite nanofiltration membrane (GDP1P2-0.6 membrane with a mean pore size = 0.87 nm) show the filtration performance with water permeance as high as 41.6 L m−2h−1bar−1and dye rejection around 99.9%, and the molecular selective factor (Eriochrome black T/Na2SO4) of α = 47.6. Long-term performance and stimulation have been investigated to further analyze the dye concentration and salt removing. The investigations demonstrate that the GO/DTiO2-PDA-PEI composite nanofiltration membrane enriches 14.9-fold Eriochrome black T (ET) and reduces Na2SO4to 0.36% in the term of the concentration factor 15 and batch diafiltration factor 5.
