How light affects 5,10,15-tris(pentafluorophenyl)corrole
How light affects 5,10,15-tris(pentafluorophenyl)corrole
复制标题
DOI：
10.1016/j.tetlet.2010.01.033
复制
发表时间：
2010-03-24
影响因子：
1.8
通讯作者：
Cavaleiro, Jose A. S.
中科院分区：
文献类型：
--
作者：
Barata, Joana F. B.;Neves, M. Graca P. M. S.;Cavaleiro, Jose A. S.
5，10，15-三（五氟苯基）咔咯在室温、空气和环境光下缓慢发生低聚反应。在不同的溶剂（氯仿、二氯甲烷和甲苯）中研究了这种转化，并鉴定了主要产物为3，3 ′-可咯二聚体2a和3，3 ′，17 ′，3 ″-可咯三聚体3a。(C)2010爱思唯尔有限公司版权所有。
5,10,15-Tris(pentafluorophenyl)corrole slowly undergoes oligomerization when left in solution at room temperature, Under air and ambient light. This transformation was Studied in different solvents (chloroform, dichloromethane, and toluene) and the main resulting products, were identified as the 3,3'-corrole dimer 2a and the 3,3',17',3 ''-corrole trimer 3a. (C) 2010 Elsevier Ltd. All rights reserved.