Aqueous C-S cross-coupling: synthesis of 2-iminobenzo-1,3-oxathioles via CuCl2•H2O-catalyzed tandem reaction of 2-iodophenols with isothiocyanates
Aqueous C-S cross-coupling: synthesis of 2-iminobenzo-1,3-oxathioles via CuCl2•H2O-catalyzed tandem reaction of 2-iodophenols with isothiocyanates
复制标题
DOI：
10.1016/j.tetlet.2011.02.061
复制
发表时间：
2011-04-20
影响因子：
1.8
通讯作者：
Peng, Yiyuan
中科院分区：
文献类型：
--
作者：
Ding, Qiuping;Liu, Xianjin;Peng, Yiyuan
介绍了CuCl2中心点h2o在水中催化2-碘酚与异硫氰酸酯的串联反应，为生成2-亚氨基苯-1,3-草硫唑提供了一条环保、高效、实用的途径。值得注意的是，通过简单的过滤，大多数产物很容易从反应体系中分离出来。(C) 2011 Elsevier Ltd.版权所有。
A CuCl2 center dot H2O-catalyzed tandem reaction of 2-iodophenol with isothiocyanate in water is described, which provides an environmentally benign, efficient, and practical route for the generation of 2-iminobenzo-1,3-oxathiole. It was noteworthy that most of the products were easily separated from the reaction system by simple filtration. (C) 2011 Elsevier Ltd. All rights reserved.