Piecing together the puzzle: understanding a mild, metal free reduction method for the large scale synthesis of hydrazines
Piecing together the puzzle: understanding a mild, metal free reduction method for the large scale synthesis of hydrazines
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DOI：
10.1016/j.tet.2011.09.146
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发表时间：
2011-12-30
期刊：
影响因子：
2.1
通讯作者：
Ley, Steven V.
中科院分区：
文献类型：
--
作者：
Browne, Duncan L.;Baxendale, Ian R.;Ley, Steven V.
本文报道了一种由重氮盐温和、无金属还原合成肼类化合物的关键中间体的分离和X-射线分析。该中间体的存在是普遍的，正如许多类似物的制备所证明的那样。还描述了这种过程的机制和潜在益处的讨论。(C)2011爱思唯尔有限公司版权所有。
A key intermediate for the synthesis of hydrazines via a mild, metal free reduction of diazonium salts has been isolated and characterized by X-ray analysis. The presence of this intermediate is general, as demonstrated by the preparation of a number of analogues. A discussion of the mechanism and potential benefits of such a process are also described. (C) 2011 Elsevier Ltd. All rights reserved.