Asymmetric benzoin reaction catalyzed by benzoylformate decarboxylase
Asymmetric benzoin reaction catalyzed by benzoylformate decarboxylase
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DOI：
10.1016/s0957-4166(99)00516-9
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发表时间：
1999-12-17
影响因子：
--
通讯作者：
Müller, M
中科院分区：
文献类型：
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作者：
Demir, AS;Dünnwald, T;Müller, M
苯甲酰甲酸脱羧酶催化 C-C 键形成，芳香醛转化为安息香。该反应以高对映体过量和良好的化学收率提供(R)-苯偶姻。多种芳香醛可用作水性缓冲液或缓冲液/DMSO 溶液中的底物。 (C) 2000 Elsevier Science Ltd. 保留所有权利。
Aromatic aldehydes are converted into benzoins by benzoylformate decarboxylase catalyzed C-C bond formation. The reaction affords (R)-benzoins with high enantiomeric excess and in good chemical yields. A broad range of aromatic aldehydes can be used as substrates in aqueous buffer or buffer/DMSO-solutions. (C) 2000 Elsevier Science Ltd. All rights reserved.