Intercalation of polyether amines into α-zirconium phosphate
Intercalation of polyether amines into α-zirconium phosphate
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DOI：
10.1039/b511351b
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发表时间：
2006-01-01
影响因子：
--
通讯作者：
Clearfield, A
中科院分区：
文献类型：
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作者：
Bestaoui, N;Spurr, NA;Clearfield, A
插层现象对包括化学在内的许多科学领域都很重要，因为在主-客体复合材料中可以结合两种材料的性质。研究了不同分子量的Jeffamine对α-磷酸锆的插层作用。层间距取决于Jeffamine的链长。用X-射线衍射、红外光谱和核磁共振谱对化合物进行了表征。层间间距高达88埃的记录。利用类似的插层剂制备环氧树脂-磷酸锆纳米复合材料。
Intercalation phenomena are important to many fields of science including chemistry because of the possibility of combining properties of two materials in a host-guest composite. The intercalation of alpha-zirconium phosphate with Jeffamines of different molecular weight is investigated. The interlayer spacing depends on the Jeffamine's chain length. The compounds are characterized by X-ray diffraction, infra-red spectroscopy and NMR. Interlayer spacings as large as 88 angstrom were recorded. Similar intercalates were utilized to prepare an epoxy resin-zirconium phosphate nanocomposite.