NUCLEOPHILIC PHOSPHINE-CATALYZED IODOCYCLIZATION OF ISOPRENOIDS BEARING AN OXYGEN TERMINAL GROUP
NUCLEOPHILIC PHOSPHINE-CATALYZED IODOCYCLIZATION OF ISOPRENOIDS BEARING AN OXYGEN TERMINAL GROUP
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DOI：
10.3987/com-09-s(e)1
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发表时间：
2010-12
期刊：
影响因子：
0.6
通讯作者：
A. Sakakura;Gakujun Shomi;Atsushi Ukai;K. Ishihara
中科院分区：
文献类型：
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作者：
A. Sakakura;Gakujun Shomi;Atsushi Ukai;K. Ishihara
研究了含氧末端基团的线性类异戊二烯的亲核膦催化非对映选择性碘环化反应。在完全非对映选择性的三苯基膦的催化作用下，均金元醇TBDMS醚和均金元酸TBDMS酯成功地转化为相应的碘多环产物。
The nucleophilic phosphine-catalyzed diastereoselective iodocyclization of linear isoprenoids bearing an oxygen terminal group was investigated. TBDMS ether of homogeraniol and TBDMS ester of homogeranic acid were successfully converted to the corresponding iodopolycyclic products in the presence of a catalytic amount of triphenylphosphine with complete diastereoselectivity.