Radical cyclisations promoted by dimanganese decacarbonyl:: A new and flexible approach to 5-membered N-heterocycles
Radical cyclisations promoted by dimanganese decacarbonyl:: A new and flexible approach to 5-membered N-heterocycles
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DOI：
10.1016/s0040-4039(99)01271-x
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发表时间：
1999-08-13
影响因子：
1.8
通讯作者：
Whittaker, DTE
中科院分区：
文献类型：
--
作者：
Gilbert, BC;Kalz, W;Whittaker, DTE
研究了用脱羰基二锰/hv进行各种不饱和卤化物的自由基环化反应。以良好至优异的产率分离取代的吡咯烷酮和吡咯烷;环化产生的自由基可以进行碘或氢原子转移，或与克里思反应。(C)1999年由爱思唯尔科学有限公司出版。保留所有权利。
Radical cyclisation of various unsaturated halides using dimanganese decarbonyf/hv has been explored. Substituted pyrrolidinones and a pyrrolidine were isolated in good to excellent yield; the radical produced on cyclisation can undergo iodine or hydrogen atom transfer, or reaction with TEMPO. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.