Experimental and Calculated Electrochemical Potentials of Common Organic Molecules for Applications to Single-Electron Redox Chemistry
Experimental and Calculated Electrochemical Potentials of Common Organic Molecules for Applications to Single-Electron Redox Chemistry
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DOI：
10.1055/s-0035-1561297
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发表时间：
2016-03-01
期刊：
影响因子：
2
通讯作者：
Nicewicz, David A.
中科院分区：
文献类型：
--
作者：
Roth, Hudson G.;Romero, Nathan A.;Nicewicz, David A.
在此，我们报告了通过循环伏安法获得的超过180种有机底物的半峰电位。这些值在评估电子转移过程的热力学方面非常有用。此外，我们还公开了一种简单的计算方法来确定有机底物的氧化还原电位。
Herein, we report half-peak potentials for over 180 organic substrates obtained via cyclic voltammetry. These values are of great use in assessing the thermodynamics of an electron-transfer process. In addition, we disclose a simple computational method to determine redox potentials of organic substrates.