Rates and Mechanisms of Substitution in Inorganic Complexes in Solution.
Rates and Mechanisms of Substitution in Inorganic Complexes in Solution.
复制标题
DOI：
10.1021/cr60155a003
复制
发表时间：
1952-02
期刊：
影响因子：
62.1
通讯作者：
H. Taube
中科院分区：
文献类型：
--
作者：
H. Taube
在一般化学或定性分析中获得的金属离子络合物形成或解离反应的经验在范围上是有限的，并且经常给人留下这样的印象，即所有这类反应都进行得非常迅速。可能因为通常没有研究行为对比的系统，所以系统的动力学方面没有引起很大的兴趣。对络合离子的化学反应有了更多的经验，例如在制备各种维尔纳络合物的过程中所获得的经验，确实揭示了大量进行缓慢的反应，事实上，许多反应进行得非常缓慢。虽然已经完成了对这些系统的一些仔细的费率研究，但是
The experience gained in general chemistry or qualitative analysis with re-actions in which metal-ion complexes are formed or dissociated is limited in scope, and often leaves the impression that all reactions of this type proceed very rapidly. Probably because no systems ofcontrasting behavior are ordinarily studied, the kinetic aspects of the systems have not excited a great deal of interest. Greater experience in the chemistry of the complex ions, such as is gained in the preparation of a variety of Werner complexes, does expose a large number of reactions which proceed slowly and many, in fact, which proceedvery slowly. Although some careful rate studies on the systems have been completed, the