A rechargeable aluminum-ion battery utilizing a copper hexacyanoferrate cathode in an organic electrolyte.

A rechargeable aluminum-ion battery utilizing a copper hexacyanoferrate cathode in an organic electrolyte.
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DOI:
10.1039/c5cc06053b
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发表时间:
2015-09
影响因子:
4.9
通讯作者:
Luke Reed;S. Ortiz;M. Xiong;E. Menke
Luke Reed;S. Ortiz;M. Xiong;E. Menke
中科院分区:
化学2区
文献类型:
--
作者:
Luke Reed;S. Ortiz;M. Xiong;E. Menke

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研究了铁氰化铜在有机电解液中的可逆铝嵌入/脱嵌行为。有证据表明,铝的溶质络合物是插入物种。该系统显示出高达60 mA h g(-1)的初始放电容量和5至14 mA h g(-1)的可逆容量,容量通常在10至15次循环后衰减。
Reversible aluminum intercalation/deintercalation from an organic electrolyte into copper hexacyanoferrate is presented. Evidence suggest that an aluminum-solute complex is the intercalating species. The system shows initial discharge capacities as high as 60 mA h g(-1) and reversible capacities between 5 and 14 mA h g(-1), with capacity typically fading after 10 to 15 cycles.