The intramolecular migration of a trimethylsilyl group located alpha to a sulfone in substituted cyclohexyl systems.
The intramolecular migration of a trimethylsilyl group located alpha to a sulfone in substituted cyclohexyl systems.
复制标题
在取代的环己基体系中，三甲基甲硅烷基在砜的α位进行分子内迁移。
DOI：
10.1002/rcm.1290040102
复制
发表时间：
1990
期刊：
影响因子：
--
通讯作者：
Fuchs,PL
中科院分区：
文献类型：
--
作者：
Wood,KV;Rothwell,AP;Anderson,MB;Fuchs,PL
本文研究了某些改性环己基环系中三甲基硅基α向砜基的分子内迁移。类似化合物的这种重排离子的相对丰度的巨大差异与质子化物质的稳定性有关。
The intramolecular migration of a trimethylsilyl moiety α to a sulfone group of some modified cylcohexyl ring systems is investigated. The large difference in the relative abundance of this rearrangement ion for similar compounds is related to the stability of the protonated species.