Theory of molecular fluids, vol. 1: Fundamentals by C. G. Gray and K. E. Gubbins, Oxford univ. press, 1985, 626 pp., $79.00
Theory of molecular fluids, vol. 1: Fundamentals by C. G. Gray and K. E. Gubbins, Oxford univ. press, 1985, 626 pp., $79.00
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分子流体理论，卷。
DOI：
10.1002/aic.690320522
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发表时间：
1986
期刊：
影响因子：
3.7
通讯作者：
Reid C. Miller
中科院分区：
文献类型：
--
作者：
Reid C. Miller
WA 99164-27，第四个问题没有写，读者被认为能够推导出这对他自己。多一点的空间致力于溶质在颗粒中通过体扩散和表面扩散的输运。然而，反应器模型部分只给出了曲线的最后重新这本书代表的结果，一个重大的承诺，审查和编纂的研究，迄今为止的分子间的力量和基本统计力学的流体组成的小，近刚性分子与一个以上的原子。治疗仅限于经典的，非反应，非电解质流体的平衡性质，特别强调液体。详细讨论了分子间势模型，特别是广义Stockmayer势和位-位势。基本的统计力学介绍集中在相关的分子分布函数和相关函数。微扰理论和积分方程理论的对相关函数，需要计算平衡性能，进行了详细讨论，适当的历史描述。广泛的附录为不太复杂的读者提供了许多有用的背景材料，包括球谐函数和相关量的信息，数学结果，分子极化率，维里和hypervirial定理。此外，还有一个相当完整的多极矩和极化率表可供应用，由于理论发展的流体包括许多化学处理中处理的物质，在化学工程中的潜在应用比以前的单原子流体理论要大得多。直接的应用将在相平衡、介电现象和表面效应等领域。对于不久的将来，这项工作将是有用的先进的研究生和某些研究工作者在化学工程热力学，与第1卷的兴趣主要是理论家。量子力学，统计力学和其他物理化学主题的良好知识将需要理解的材料，而无需扩展自学或tutaledge-可能的知识水平
WA 99164-27, 4 tion is not written, the reader is assumed to be able to derive this on his own. A little more space is devoted to the transport of solute in the particles by bulk and sur-face diffusion. However, the reactor models section gives only curves of final re-This book represents the results of a major undertaking to review and codify the research to date on intermolecular forces and fundamental statistical mechanics for fluids composed of small, nearly-rigid molecules with more than one atom. The treatment is restricted to equilibrium properties of classical, nonreacting, nonelectrolyte fluids, with particular emphasis on liquids. Intermolecular potential models are discussed in great detail, especially the generalized Stockmayer potential and the site-site potential. The fundamental statistical mechanics presentation focuses on the pertinent molecular distribution functions and correlation functions. Both perturbation theories and integral equation theories for the pair correlation function, needed to calculate equilibrium properties, are discussed in much detail, with appropriate historical descriptions. Extensive appendices provide much useful background material for the less sophisticated reader, including information on spherical harmonics and related quantities, mathematical results, molecular polarizabilities, and the virial and hypervirial theorems. In addition, there is a rather complete table of multipole moments and polarizabilities for use in applications, Since the fluids for which the theories are developed include many species dealt with in chemical processing, the potential applications in chemical engineering are of a much greater magnitude than previous theories of monatomic fluids. Direct applications would be in such areas as phase equilibria, dielectric phenomena, and surface effects. For the immediate future, this work will be useful to advanced graduate students and certain research workers in chemical engineering thermodynamics, with Volume 1 of interest primarily to theorists. A good knowledge of quantum mechanics, statistical mechanics, and other physical chemistry topics will be needed to comprehend the material without extended self study or tutaledge-probably a level of knowledge