Synthesis, crystal structure, and properties of a new hydrogen-bonded electron-donor: 1,6-Dithiapyrene-imidazole
Synthesis, crystal structure, and properties of a new hydrogen-bonded electron-donor: 1,6-Dithiapyrene-imidazole
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DOI：
10.1016/j.solidstatesciences.2008.01.010
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发表时间：
2008-12-01
影响因子：
3.5
通讯作者：
Nakasuji, Kazuhiro
中科院分区：
文献类型：
--
作者：
Morita, Yasushi;Yakiyama, Yami;Nakasuji, Kazuhiro
设计并合成了一种新型的含咪唑基团的1，6-二硫杂芘（DTPY）衍生物--DTPY-咪唑。用CV法测定的给电子体的给电子能力与DTPY相似。该分子由一维氢键链和一维氢键堆积柱构成二维网络结构。TCNQ配合物的红外光谱和电子光谱表明，该配合物为部分电荷转移配合物，具有偏聚结构，并具有较高的电导率（290 K时为5.6 × 10（-2）S cm（-1））。(C)2008年，Elsevier Masson SAS。All rights reserved.
1,6-Dithiapyrene (DTPY) derivative having an imidazole moiety, DTPY-imidazole, was designed and synthesized as a new hydrogen-bonded electron-donor molecule. The electron-donating ability of the donor estimated by CV measurement was similar to that of DTPY. This molecule formed a two-dimensional network structure involving a one-dimensional H-bonded chain and it-stacking column. The TCNQ complex was characterized as a partial charge-transfer complex having a segregated structure from the IR and electronic spectra and exhibited a high electrical conductivity (5.6 x 10(-2) S cm(-1) at 290 K). (C) 2008 Elsevier Masson SAS. All rights reserved.