Reductive electrochemical decomposition of chloroform on metal electrodes
Reductive electrochemical decomposition of chloroform on metal electrodes
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DOI：
10.1246/cl.1997.131
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发表时间：
1997-01-01
影响因子：
1.6
通讯作者：
Sakata, T
中科院分区：
文献类型：
--
作者：
Sonoyama, N;Hara, K;Sakata, T
用15种金属电极对氯仿进行了电化学还原分解。金属电极对分解效率和主要产物的影响很大。氯仿在Ag、Zn、Pd和Cu电极上的加氢效率约为100%。这些电极主要产生甲烷。铅电极选择性产生二氯甲烷。
The electrochemical reductive decomposition of chloroform was carried out using 15 kinds of metal electrodes. The efficiency of the decomposition and the main product of reaction largely depended on the metal electrodes. The hydrogenation of chloroform by Ag, Zn, Pd and Cu electrodes proceeded in about 100% efficiency. These electrodes produced methane mainly. Pb electrode produced dichloromethane selectively.